Bis(μ-2,2′-{[4-(carboxymethoxy)phenyl]azanediyl}diacetato)bis[(1,10-phenanthroline)copper(II)]
نویسندگان
چکیده
The crystal structure of the binuclear title compound, [Cu(2)(C(12)H(11)NO(7))(2)(C(12)H(8)N(2))(2)], consists of a complex mol-ecule, which lies about a crystallographic inversion centre with one half-mol-ecule in the asymmetric unit. The Cu(II) cation is bonded to three N atoms and three O atoms, in a Jahn-Teller-distorted octa-hedral geometry. The basal plane is defined by the two N atoms from the 1,10-phenathroline and two deprotonated O atoms of the polycarboxyl-ate ligand. The axial positions are occupied by the azane N atom and a bridging carboxyl-ate O atom from the second polycarboxyl-ate ligand. The complex mol-ecules are linked through O-H⋯O hydrogen bonds into extended chains running parallel to [010].
منابع مشابه
Synthesis and Structure of Dimeric Copper (I) Complex from Bis[(2,2’)-dimethyl2,2’-(1,10-phenanthroline-2,9-diyl)bis(methan-1-yl-1-ylidene)-bis(hydrazinecarbo dithioate)]
Metal complex, bis[(2,2’)-dimethyl 2,2’-(1,10-phenanthrline-2,9-diyl)bis(methan-1-yl-1-ylidene)-bis(hydrazinecarrbo dithioate)copper(I)], was synthesized from the reaction of Schiff base, (2,2’)-dimethyl 2,2’-(1,10-phenanthroline-2,9diyl)bis(methan-1-yl-1-ylidene)-bis(hydrazinecarbo dithioate) and CuCl2 at reflux condition in methanol. The copper centers of the complex appear to be reduced. Thi...
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The title complex, [Cu(2)(C(7)H(6)NO(2))(2)(C(12)H(8)N(2))(2)(H(2)O)(2)]·2C(7)H(7)NO(2)·2H(2)O, consists of a dinuclear [Cu(2)(C(7)H(6)NO(2))(2)(C(12)H(8)N(2))(2)(H(2)O)(2)](2+) cation, two Cl(-) anions, two 4-amino-benzoic acid mol-ecules and two disordered water mol-ecules (site occupancy factors 0.5). The Cu(II) ion adopts a distorted square-pyramidal geometry formed by two N atoms from the ...
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The title complex, {[Mn(C(14)H(8)O(4)S(2))(C(12)H(8)N(2))(2)]·0.5CH(3)OH·H(2)O}(n), has a one-dimensional chain structure in which the Mn(II) atom is six-coordinated by four N atoms from two 1,10-phenanthroline (phen) ligands and two O atoms from two 2,2'-dithio-dibenzoate (L) ligands. The L ligands adopt a bis-(monodentate) (syn-anti) coordination mode and bridge adjacent Mn(II) centres, gener...
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عنوان ژورنال:
دوره 66 شماره
صفحات -
تاریخ انتشار 2010